期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 9, 页码 3162-3165出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511197
关键词
C-H activation; chelation assistance; methylation; nickel; phenyltrimethylammonium iodide
资金
- Ministry of Education, Culture, Sports, Science and Technology
- JST Strategic Basic Research Programs from Japan Science and Technology Agency
Methylation of C(sp(2))-H bonds was achieved through the Ni-II-catalyzed reaction of benzamides with phenyltrimethylammonium bromide or iodide as the source of the methyl group. The reaction has a broad scope and shows high functional-group compatibility. The reaction is also applicable to the methylation of C(sp(3))-H bonds in aliphatic amides.
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