期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 9, 页码 3166-3170出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511251
关键词
arylation; carborane; heterocycles; photocatalysis; radicals
资金
- Research Grants Council of the Hong Kong Special Administration Region [CUHK7/CRF/12G]
- National Basic Research Program of China (973 Program) [2012CB821600]
- NSFC-RGC Joint Research Scheme [N_CUHK442/14]
A visible-light-mediated insitu generation of a boron-centered carboranyl radical (o-C2B10H11.) has been described. With eosinY as a photoredox catalyst, 3-diazonium-o-carborane tetrafluoroborate [3-N-2-o-C2B10H11][BF4] was converted into the corresponding boron-centered carboranyl radical intermediate, which can undergo efficient electrophilic substitution reaction with a wide range of (hetero)arenes. This general and simple procedure provides a metal-free alternative for the synthesis of 3-(hetero)arylated-o-carboranes.
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