期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 5, 页码 1214-1218出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201610070
关键词
electron transfer; exciton migration; fluorescence quenching; fullerenes; perovskite nanocrystals
资金
- MEXT under the JSPS [15H01099]
- DST [SR/S2/RJN-133/2012]
- DST-SERI [DST/TM/SERI/FR/121]
- CSIR
- Research Grant Council of Hong Kong S.A.R. [CityU 11337616]
- Grants-in-Aid for Scientific Research [15H01099] Funding Source: KAKEN
Hydrophobically capped nanocrystals of formamidinium lead bromide (FAPbBr(3)) perovskite (PNC) show bright and stable fluorescence in solution and thin-film states. When compared with isolated PNCs in a solution, closepacked PNCs in a thin film show extended fluorescence lifetime (ca. 4.2 mu s), which is due to hopping or migration of photogenerated excitons among PNCs. Both fluorescence quantum efficiency and lifetime decrease in a PNC thin film doped with fullerene (C-60), which is attributed to channeling of exciton migration into electron transfer to C-60. On the other hand, quenching of fluorescence intensity of a PNC solution is not accompanied by any change in fluorescence lifetime, indicating static electron transfer to C-60 adsorbed onto the hydrophobic surface of individual PNCs. Exciton migration among close-packed PNCs and electron transfer to C-60 places C-60-doped PNC thin films among cost-effective antenna systems for solar cells.
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