期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 2, 页码 650-654出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201610693
关键词
amines; aziridines; desymmetrization; kinetic resolution; silver
资金
- National Natural Science Foundation of China (NSFC) [21202001, 21472001, 21432001]
- National Basic Research Program of China [2012CB821600]
- Special and Excellent Research Fund of Anhui Normal University
The kinetic resolution of 2-aryl-N-tosylaziridines and the asymmetric desymmetrization of meso-N-tosylaziridines by ring openings with various primary and secondary anilines, and aliphatic amines as nucleophile have been realized by using a single silver(I)/chiral diphosphine complex as catalyst for the first time. The simple starting materials, broad scope, and easy scalability render this protocol a practical way to chiral vicinal diamine derivatives.
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