期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 29, 页码 8381-8385出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201603659
关键词
azides; density functional calculations; redox chemistry; ruthenium; structure determination
资金
- European Research Council (ERC) [279097]
Coordination of a redox-active pyridine aminophenol ligand to Ru-II followed by aerobic oxidation generates two diamagnetic Ru-III species [1a (cis) and 1b (trans)] with ligand-centered radicals. The reaction of 1a/1b with excess NaN3 under inert atmosphere resulted in the formation of a rare bis(nitrido)-bridged trinuclear ruthenium complex with two nonlinear asymmetrical Ru-N-Ru fragments. The spontaneous reduction of the ligand centered radical in the parent 1a/1b supports the oxidation of a nitride (N-3(-)) to half an equivalent of N-2. The trinuclear omplex is reactive toward TEMPO-H, tin hydrides, thiols, and dihydrogen.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据