期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 46, 页码 14367-14370出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201607579
关键词
alkenes; carbonyl compounds; hydroboration; manganese catalysis; Markovnikov selectivity
资金
- American Chemical Society [54247-UNI3]
- CUNY Collaborative Research Incentive Program
- PSC-CUNY award [69069-0047]
- Office for the Advancement of Research
- Program for Research Initiatives for Science Majors (PRISM) at John Jay College, CUNY
- National Science Foundation (NSF) [CHE-1464543]
- NSF [0840444]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1464543] Funding Source: National Science Foundation
Well-defined manganese complexes based on inexpensive, readily available ligands, 2,2': 6', 2 ''-terpyridine and its derivatives have been prepared and employed for the selective hydroboration of alkenes, ketones and aldehydes. Highly Markovnikov regioselective hydroboration of styrenes as well as excellent chemoselective hydroboration of ketones over alkenes were achieved, for the first time, by an earth-abundant manganese catalyst.
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