期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 6, 页码 2248-2251出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201507630
关键词
alkenes; amino alcohols; bioactive compounds; homogeneous catalysis; iron
资金
- Max-Planck-Society
- Max-Planck-Institut fur Kohlenforschung
Aryl-substituted amino alcohols are privileged scaffolds in medicinal chemistry and natural products. Herein, we report that an exceptionally simple and inexpensive Fe-II complex efficiently catalyzes the direct transformation of simple alkenes into unprotected amino alcohols in good yield and perfect regioselectivity. This new catalytic method was applied in the expedient synthesis of bioactive molecules and could be extended to aminoetherification.
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