期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 6, 页码 2226-2229出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510418
关键词
amidyl radicals; electrochemistry; ferrocene; hydroamidation; redox catalysts
资金
- XMU
- NSFC [21402164]
- Thousand Youth Talents Plan
- Fundamental Research Funds for the Central Universities
Oxidative generation of synthetically important amidyl radicals from N-H amides is an appealing and yet challenging task. Previous methods require a stoichiometric amount of a strong oxidant and/or a costly noble-metal catalyst. We report herein the first electrocatalytic method that employs ferrocene (Fc), a cheap organometallic reagent, as the redox catalyst to produce amidyl radicals from N-aryl amides. Based on this radical-generating method, an efficient intramolecular olefin hydroamidation reaction has been developed.
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