期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 37, 页码 11120-11123出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604952
关键词
1; 7-enynes; acenes; cycloaddition; gold(I) catalysis; Sonogashira coupling
A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a Au-I-catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.
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