期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 24, 页码 6951-6953出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601758
关键词
cyclooctynes; diene isomerization; heterobimetallic complexes; hydrides; zirconium
资金
- Royal Society
- EPSRC [EP/L011514/1]
- EPSRC [EP/L011514/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/L011514/1] Funding Source: researchfish
Reaction of a zinc/zirconium heterobimetallic complex with 1,5-cyclooctadiene (1,5-COD) results in slow isomerization to 1,3-cyclooctadiene (1,3-COD), along with the formation of a new complex that includes a cyclooctyne ligand bridging two metal centers. While analogous magnesium/zirconium and aluminum/zirconium heterobimetallic complexes are competent for the catalytic isomerization of 1,5-COD to 1,3-COD, only in the case of the zinc species is the cyclooctyne adduct observed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据