4.4 Article

Gold/photoredox-cocatalyzed atom transfer thiosulfonylation of alkynes: Stereoselective synthesis of vinylsulfones

期刊

TETRAHEDRON LETTERS
卷 60, 期 13, 页码 916-919

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.02.039

关键词

Sulfur chemistry; Radical reaction; Photocatalysis

资金

  1. National Natural Science Foundation of China [21572118, 21750110444]
  2. Tang Scholar Award from Shandong University

向作者/读者索取更多资源

We report a gold and photoredox combined radical approach for the rapid synthesis of thio-functionalized vinylsulfones from alkynes. Key features of this method include very mild conditions, broad substrate scope, excellent regio- and stereoselectivties, and 100% atom economy. (C) 2019 Elsevier Ltd. All rights reserved.

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