期刊
SMALL
卷 15, 期 14, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201805465
关键词
heterojunction structure; magnetic microspheres; mesoporous organosilica; pickering emulsion catalysis; yolk-shell structure
类别
资金
- NSF of China [51372041, 51422202, 21673048, 21875044]
- Key Basic Research Program of Science and Technology Commission of Shanghai Municipality [17JC1400100]
- State Key Basic Research Program of the PRC [2016YFA0204000]
- Youth Top-notch Talent Support Program of China
Using interfacial reaction systems for biphasic catalytic reactions is attracting more and more attention due to their simple reaction process and low environmental pollution. Yolk-shell structured materials have broad applications in biomedicine, catalysis, and environmental remediation owing to their open channels and large space for guest molecules. Conventional methods to obtain yolk-shell mesoporous materials rely on costly and complex hard-template strategies. In this study, a mild and convenient nonsacrificial self-template strategy is developed to construct yolk-shell magnetic periodic mesoporous organosilica (YS-mPMO) particles by using the unique swelling-deswelling property of low-crosslinking density resorcinol formaldehyde (RF). The obtained YS-mPMO microspheres possess an amphiphilic outer shell, high surface area (393 m(2) g(-1)), uniform mesopores (2.58 nm), a tunable middle hollow space (50-156 nm), and high superparamagnetism (34.4-37.1 emu g(-1)). By tuning the synthesis conditions, heterojunction structured yolk-shell Fe3O4@RF@void@PMO particles with different morphologies can be produced. Owing to the amphipathy of PMO framworks, the YS-mPMO particles show great emulsion stabilization ability and recyclability under a magnetic field. YS-mPMO microspheres with immobilized Au nanoparticles (approximate to 3 nm) act as both solid emulsifier for dispersing styrene (St) in water and interface catalysts for selective conversion of St into styrene oxide with a high selectivity of 86%, and yields of over 97%.
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