期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 210, 期 -, 页码 995-1000出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.seppur.2018.09.041
关键词
Pyrrolidinone; Hypercrosslinked polymers; Iodine; Capture
资金
- State Key Laboratory of Supramolecular Structure and Materials, Jilin University, China [sklssm201815]
The potential consequences of radioactive iodine motivate the development of highly effective adsorbents with facile synthesis strategies. Pyrrolidinone was herein employed as the monomer to prepare hypercrosslinked polymers (HCPs) via a simple Friedel-Crafts reaction catalyzed by FeCl3. Owing to the affinity sites of pyrrolidinone toward iodine, high surface area, and electron-rich aromatic networks of HCPs, the developed pyrrolidinone-based HCPs exhibited an iodine uptake capacity up to 460 wt%. Our work highlighted new opportunities in using HCPs as a platform for iodine capture from nuclear waste for environment remediation by taking advantages of their facile synthesis and low cost.
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