The perchlorate record during 1956-2004 from Tienshan ice core, East Asia

Perchlorate concentration in a shallow ice core at Tienshan, East Asia ranged between 0.55 and 52.1 ng L-1, with significant temporal variations during 1956-2004. Since the 1980s, a clear increasing trend of perchlorate was observed in the Miaoergou ice core, possibly the result of elevated stratospheric chlorine levels caused by emissions of anthropogenic volatile chlorine compounds. Although differences in trends and amounts were observed, the 1956-2004 perchlorate data from this study compares well with the perchlorate data from the High Arctic ice cores. The spatial and temporal differences of the perchlorate in Miaoergou ice core may be due to differences in anthropogenic sources. Such as, the nitrate ore field in Turpan-Hami Basin in eastern Xinjiang, China, may be the primary anthropogenic source. From the organic chlorine species emission data, HCFC-141b, HCFC-142b and HCFC-124 were identified as the primary anthropogenic sources responsible for the two perchlorate spikes observed for 1980-1996 and 1997-2001. The Miaoergou ice core covering the 1956-2004 period provides further evidence for the perchlorate deposition variations between mid-latitudes and the High Arctic regions. (C) 2018 Elsevier B.V. All rights reserved.