期刊
POLYMER
卷 163, 期 -, 页码 171-177出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2018.12.055
关键词
Graphene; Nanocomposites; Mechanical properties; Interface characterization
资金
- Key Research and Development Projects of Shaanxi Province [2017ZDXM-GY-050]
- Electrical Materials and Infiltration Key Laboratory of Shaanxi Province Projects [17JS080]
- UK Engineering and Physical Sciences Research (EPSRC) [EP/P018998]
- Newton Mobility Grant through Royal Society [IE161019]
- Newton Mobility Grant through National Natural Science Foundation of China [IE161019]
- Royal academy of Engineering UK-Research Exchange with China
- Royal academy of Engineering UK-Research Exchange with India
- Scientific Research Program of Northwest Institute for Nonferrous Metal Research [K1652-1]
Graphene/epoxy resin nanocomposites were prepared using an in-situ polymerization process, and their formation mechanisms, microstructures, mechanical properties and electrical conductivity were characterized. Results showed that graphene is well dispersed in the epoxy matrix, and covalent cross-links are formed between graphene and epoxy matrix. Tensile strength and modulus of the graphene/epoxy composites were found to increase firstly and then decrease with the increase of graphene loading contents. When the graphene content was 0.3 wt%, tensile strength, tensile modulus and elongation were found to increase by 46.8%, 47.3% and 24.0% compared with those of pure epoxy resin. When the graphene content was 1.38 vol%, the conductivity of the composite was 3.28 x 10(-4) S m(-1) with a low percolation threshold of 0.47 vol%. Enhancement mechanisms for the properties of composites were identified to be dispersion strengthening, effective transfer of stress and bridging of graphene.
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