期刊
ORGANOMETALLICS
卷 38, 期 4, 页码 870-878出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00853
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资金
- Science & Engineering Research Board (SERB), New Delhi [EMR/2017/000620]
- Department of Atomic Energy (DAE)
- CSIR
- SERB
A series of B <- N coordinated tetrahydrodibenzo[a,i]phenanthridine-based polycyclic aromatic hydrocarbons (PAHs) have been designed and synthesized. All of these compounds have been characterized by multinuclear NMR spectroscopy and high-resolution mass spectrometry. Compounds 1, 2, 4, and 7 have also been characterized by single-crystal X-ray diffraction analysis. Our newly synthesized compounds exhibit good luminescence quantum yields in solution and moderate quantum yields in the solid state. Furthermore, the compounds show a large Stokes shift in comparison to the well-known boron-dipyrromethene dyes.
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