期刊
ORGANOMETALLICS
卷 38, 期 3, 页码 610-613出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00938
关键词
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资金
- JSPS [KAKENHI 17H01191, 17K19128]
- JST [CREST 14529307]
- Grants-in-Aid for Scientific Research [17K19128] Funding Source: KAKEN
Germabenzene bearing a reactive chlorine group on the germanium atom was generated and characterized by nuclear magnetic resonance spectroscopy. Reactions of the in situ generated chlorogermabenzene with aryllithium reagents gave isolable germabenzenes bearing aryl groups, such as mesityl or acridinyl groups, on the germanium atom. This reaction constitutes the first example for a nucleophilic aromatic substitution of heavy heterobenzenes at the main group center.
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