期刊
ORGANIC LETTERS
卷 21, 期 7, 页码 1994-1998出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00071
关键词
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资金
- Foundation Research Project of Jiangsu Province (The Natural Science Foundation) [BK20180513]
- Fundamental Research Funds for the Central Universities [KYDZ201904]
- 333 High Level Talent Project of Jiangsu Province
- China Postdoctoral Science Foundation [2018M630563]
An efficient method for highly selective alkenyl C-P bond cleavage, enabled by organic dyes and visible-light irradiation, was developed. This novel protocol involves a highly regioselective radical pathway initiated by singlet oxygen, affording diverse alkynyl phosphinates with good-to-excellent yields. Mechanistic studies and density functional theory calculations suggested an intramolecular process involving phosphorus migration, instead of phosphorus radical formation, at the early stage of the reaction.
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