期刊
ORGANIC LETTERS
卷 21, 期 7, 页码 2048-2051出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00216
关键词
-
资金
- NSFC [21672197, 21772184]
- Chinese Academy of Science [XDB20000000]
The first Pd(II)-catalyzed asymmetric oxidative annulation of N-alkoxyaryl amides and 1,3-dienes is reported, which features particular applicability for quick assembly of different types of chiral heterocycles with high yields and enantioselectivities. A novel chiral pyridine-oxazoline bearing a methoxyl group at the C-5 position and a gem-dimethyl group on the oxazoline moiety was found to be crucial for conversion.
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