期刊
ORGANIC LETTERS
卷 21, 期 6, 页码 1809-1812出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00391
关键词
-
资金
- 973 program [2015CB856600]
- NSFC [21871010]
A Cu(I)-catalyzed cross-coupling reaction of bis(trimethylsilyl)diazomethane and benzoxazoles/oxazoles is reported. A wide range of functional groups can be tolerated in this transformation. This reaction provides a new method to directly introduce a 1,1-bis(trimethylsilyl)methyl group into heteroaromatic C-H bonds. Subsequent transformations of 1,1-bis(trimethylsilyl)-methylated heteroaromatic compounds are also presented.
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