期刊
ORGANIC LETTERS
卷 21, 期 6, 页码 1722-1725出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00278
关键词
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资金
- JSPS [KAKENHI 17H01191, 17K19128]
- CREST from JST [14529307]
- Grants-in-Aid for Scientific Research [17K19128] Funding Source: KAKEN
Chlorine-substituted 9,10-dihydro-9-aza-10-boraanthracene was synthesized. Derivatization of this compound by taking advantage of the transformable B Cl moiety gave 9,10-dihydro-9-aza-10-boraanthracene derivatives with various aryl substituents. In addition, further functionalization on NH groups by alkylation and Buchwald-Hartwig amination was demonstrated. Photophysical properties of the resulting 9,10-dihydro-9-aza-10-boraanthracene derivatives were also discussed.
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