期刊
ORGANIC LETTERS
卷 21, 期 5, 页码 1480-1483出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00266
关键词
-
资金
- National Natural Science Foundation of China [21672259]
Nitration-peroxidation of alkenes for the synthesis of beta-peroxyl nitroalkanes has been developed by using tert-butyl nitrite and tert-butyl hydroperoxide. The method presents a new and selective difunctionalization of alkenes to introduce a nitro group and a peroxyl group across the double bonds of alkenes under mild conditions. A radical reaction pathway is proposed by experimental and theoretical studies.
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