期刊
ORGANIC LETTERS
卷 21, 期 5, 页码 1297-1300出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03274
关键词
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资金
- National Natural Science Foundation of China [21702081, 21702150]
- China Post-doctoral Science Foundation [BX201600114, 2016M602340]
- Jiangxi Provincial Education Department Foundation [GJJ160325]
The use of additive-free conditions is an ideal approach to prepare organoselenium reagents from readily available unsaturated substrates. Thus, we report the electro-induced aminoselenation and oxyselenation of styrenes without any acids or oxidants as additives. This transformation is compatible with various functional groups, which leads to vicinal difunctionalized organoselenium compounds. Our strategy improves the potential of this protocol for use in the pharmaceutical industry. Based upon the preliminary mechanism studies, we propose two possible pathways.
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