期刊
ORGANIC LETTERS
卷 21, 期 5, 页码 1412-1416出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00148
关键词
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资金
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- 1000-Youth Talents Plan
- NSF of China [21772220, 21821002]
- S&TCSM of Shanghai [17JC1401200, 18JC1415600]
Palladium-catalyzed transfer semihydrogenation of alkynes using H2O as the hydrogen source and Mn as the reducing reagent is developed, affording cis- and trans-alkenes selectively under mild conditions. In addition, this method provides an efficient way to access various cis-1,2-dideuterioalkenes and trans-1,2-dideuterioalkenes by using D2O instead of H2O.
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