期刊
ORGANIC LETTERS
卷 21, 期 7, 页码 2147-2150出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00459
关键词
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资金
- Natural Science Foundation of Shandong Province [ZR2016BQ24]
- Natural Science Foundation of China [21703116, 51702180]
A new porous organic polymer has been prepared via copolymerization of divinyl-functionalized phosphoramidite ligand and tris(4-vinylphenyl)phosphine. The porous polymer was loaded with Rh(acac)CO2 to yield a supported Rh catalyst, which demonstrated good regioselectivity (l/b = 6.7-52.8) and high catalytic activity (TON up to 45.3 x 10(4)) in hydroformylation of terminal and internal olefins. Remarkably, the heterogeneous catalyst can be reused at least 10 cycles without losing activity and selectivity in hydroformylation of 1-hexene.
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