期刊
ORGANIC LETTERS
卷 21, 期 5, 页码 1354-1358出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00057
关键词
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资金
- European Union [696656]
- German Research Foundation (DFG) [391979941]
- European Social Fund
- Federal State of Saxony (ESF-Project GRAPHD, TU Dresden)
- China Scholarship Council (CSC)
Two novel nonhexagonal ring fused NBN-dibenzophenalenes (NBN-penta and NBN-hepta) were designed and synthesized. X-ray analysis reveals the planar structure of NBN-penta, while NBN-hepta displays a double-helical structure. Both compounds possess higher oxidation potential compared to the NBN-type zigzag-edged polycyclic aromatic hydrocarbons. The resultant NBN-penta and NBN-hepta exhibit global aromatic character based on X-ray analysis and DFT calculations. Furthermore, single crystal transistors of NBN-penta and NBN-hepta were fabricated, manifesting their promising potential in organic electronics.
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