期刊
NANOSCALE RESEARCH LETTERS
卷 14, 期 -, 页码 -出版社
SPRINGEROPEN
DOI: 10.1186/s11671-019-2900-7
关键词
Zinc oxide; Graphene aerogel; Atomic layer deposition; Capacity increase; Lithium-ion batteries
资金
- Natural Science Foundation of China [61628401, U1632115]
- Science and Technology Commission of Shanghai Municipality [17JC1401700]
- Changjiang Young Scholars Program of China
- National Key Technologies R&D Program of China [2015ZX02102-003]
Zinc oxide (ZnO) nanomembranes/graphene aerogel (GAZ) composites were successfully fabricated via atomic layer deposition (ALD). The composition of GAZ composites can be controlled by changing the number of ALD cycles. Experimental results demonstrated that the anode made from GAZ composite with ZnO nanomembrane of 100 ALD cycles exhibited highest specific capacity and best rate performance. A capacity increase of more than 2 times during the first 500cycles was observed, and a highest capacity of 1200mAhg(-1) at current density of 1000mAg(-1) was observed after 500cycles. On the basis of detailed electrochemical investigations, we ascribe the remarkable cycling-induced capacity increase to the alloying process accompanied by the formation of a polymer layer resulting from kinetically activated electrolyte degradation at low voltage regions.
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