期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 276, 期 -, 页码 68-75出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2018.09.017
关键词
Magnetic; UiO-66; MOFs; Adsorption; Arsenic removal
类别
资金
- National Natural Science Foundation of China [51778598, 51478449]
- International Science & Technology Cooperation Program of China [2011DFB91710]
Facile fabrication of magnetic metal-organic frameworks (MOFs) using a direct epitaxial approach for eliminating arsenic from water is highly desirable. Herein, a two-step solvothermal method of elegant design is proposed to synthesize Fe3O4@UiO-66. Such resulting composite was systematically characterized using powder X-ray diffraction (PXRD), Fourier transform infrared (FUR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N-2 adsorption-desorption isotherms, and thermogravimetric analysis (TGA). Results clearly reveal that this novel composite exhibits a unique core-shell structure with high specific surface area and plentiful micropores as well as good thermal stability. Specifically, batch adsorption data for arsenate demonstrate that a pseudo-second order kinetic model (R-2 = 0.9996) better describes this adsorption process than a pseudo-first order model (R-2 = 0.8582), revealing the chemical interaction between the composite and arsenate. The Freundlich model with better coefficient (R-2 = 0.9566) further verified multi-layer heterogeneous adsorption, which may be ascribed to the unique core-shell structure of this composite (Fe3O4@UiO-66). Its excellent adsorption performance for arsenate (73.2 mg (As) g(-1) (adsorbent)) is comparable to most MOFs-containing adsorbents but is also magnetic, allowing for ready separation of the composite from aqueous solution. Given this combination of qualities, this new composite could offer a promising alternative for wastewater remediation.
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