期刊
MENDELEEV COMMUNICATIONS
卷 29, 期 1, 页码 25-28出版社
ELSEVIER
DOI: 10.1016/j.mencom.2019.01.007
关键词
-
资金
- Russian Science Foundation [14-50-00126]
- Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of the National University of Science and Technology 'MISTS' [K2-2017-011]
The influence of structural differences in cis- and trans-conformer molecules of ortho-, meta- and para-isomers of perhydroterphenyl and decalin on the hydrogen release in hydrogen storage systems was estimated for the Pt/C catalyst in a flow regime. The structural differences between the cis- and trans-conformers of perhydroterphenyl did not significantly affect the reactivity of its ortho-, meta- and para-isomers. In the case of decalin, the decrease in the volume of released hydrogen due to the conversion of its cis-isomer into the less active trans-form was clearly demonstrated.
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