期刊
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
卷 408, 期 28, 页码 8211-8220出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s00216-016-9931-z
关键词
Affinity capillary electrophoresis; Binding constants; Cyclodextrin; Ionic liquid; Isothermal titration calorimetry
The state of the art of inclusion complex formation between cyclodextrins and ionic liquids is reported. Mechanisms, stoichiometries, and binding constants are summarized and classified by anion. We investigated the supramolecular interactions between the beta-cyclodextrin cavity and six ionic liquids based on 1-dodecyl-3-methylimidazolium by affinity capillary electrophoresis and compared the results with those obtained by isothermal titration calorimetry. We show that the presence of basic or acidic buffers leads to a metathesis reaction, underlining the limitation of the affinity capillary electrophoresis technique.
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