期刊
MATERIALS RESEARCH BULLETIN
卷 111, 期 -, 页码 170-176出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2018.11.001
关键词
Lithium ion batteries; Fe3O4 anode; Graphene; Polypyrrole; Polymer derived carbon
资金
- National Natural Science Foundation of China [51602310]
- DNL Cooperation Fund, CAS [180308]
- Fujian Provincial Department of Science and Technology [2018H0041, 2018H0042, 2016T3027, 2016T3031, 2018T3010]
Combining graphene with iron oxide has shown great promise in mitigating the pulverization of iron-oxide anode during fast charge/discharge in lithium-ion batteries. However, the attachment between hydrophilic iron oxide and hydrophobic graphene sheets could potentially compromise during cycling, affecting its cycling stability. By exploiting the polymerization characteristics of pyrrole, we anchor and subsequently wrap the Fe(OH)(3) colloidal nanoparticles onto graphene oxide surface with polypyrrole. The composite is further annealed to give polypyrrole-derived-carbon (PPy-C) wrapped Fe3O4@graphene (Fe3O4@graphene@PPy-C). PPy-C strengthens the interaction between the Fe3O4 and the graphene and helps preserving the structural integrity during cycling. As an anode material, Fe3O4@graphene@PPy-C composite exhibits a high reversible capacity of 721 mA h g(-1) over 320 cycles at a current density of 0.2 A g(-1). Even at a high current density of 2A g(-1), the electrode still achieves a high capacity of 406 mA h g(-1). This strategy provides a new alternative to improve the cycling stability of iron-oxide/carbon composite anodes.
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