期刊
MACROMOLECULES
卷 52, 期 3, 页码 935-944出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.8b02528
关键词
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资金
- JSPS KAKENHI [18H02020]
- Natural Science and Research Council of Canada
- Grants-in-Aid for Scientific Research [18H02020] Funding Source: KAKEN
Suitably end-functionalized diblock copolymers (2-isopropyl-2oxazoline)-b-(2-ethyl-2-oxazoline) (PIPOZ-b-PEOZ) were linked to a tetrafunctional core to synthesize two isomeric thermosensitive 4-arm star block polymers which have the PIPOZ block near the core, core-(PIPOZ-bPEOZ)(4), or near the outer surface the star polymer, core-(PEOZ-b-PIPOZ)(4) The solution properties of the star copolymers in water were monitored by turbidimetry, microcalorimetry, and small-angle X-ray scattering (SAXS). The dehydration and cloud-point temperatures of both core-(PIPOZ-b-PEOZ)(4) and core-(PEOZ-b-PIPOZ)(4) in water are in the vicinity of 50 degrees C. Above this temperature, core-(PIPOZ-b-PEOZ)(4) forms starlike aggregates or star micelle, whereas core-(PEOZ-b-PIPOZ)(4) remains isolated, with no sign of aggregation. These results demonstrate the importance of chain architecture on the association of thermosensitive tetra-arm star block copolymers in water above the dehydration temperature.
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