期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 14, 页码 5669-5674出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b02552
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资金
- Yale University
- Sloan Foundation
- Nalas Engineering
- Amgen
- NSF (CAREER) [1653793]
- NIH [T32GM067543]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1653793] Funding Source: National Science Foundation
We herein disclose the first report of a first-row transition metal-catalyzed alpha,beta-dehydrogenation of carbonyl compounds using allyl-nickel catalysis. This development overcomes several limitations of previously reported allyl-palladium-catalyzed oxidation, and is further leveraged for the development of an oxidative cycloalkenylation reaction that provides access to bicycloalkenones with fused, bridged, and spirocyclic ring systems using unactivated ketone and alkene precursors.
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