期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 11, 页码 4521-4525出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b13207
关键词
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资金
- NSERC
- AFOSR [FA9550-18-1-04999]
- ONR [N00014-17-1-2231]
(4NPEA)(2)PbI4 (4NPEA = 4-nitrophenylethylammonium) is the first 3 X 3 corrugated 2D organic-Pb/I perovskite. The nitro groups are involved in cation-cation and cation-iodide interactions. The structure contains both highly distorted and near-ideal PbI6 octahedra, consistent with the observation of two Pb-207 NMR resonances, while the optical properties resemble those of other 2D perovskites with distorted PbI6 octahedra.
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