期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 11, 页码 4696-4703出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b13865
关键词
-
资金
- Japan Society for the Promotion of Science (JSPS) KAKENHI [17K05875]
- Air Force Office of Scientific Research [17RT0904]
Here we report an efficient synthesis of optically active ladder-type molecules and polymers through intramolecular cyclization of chiral triptycenes containing bis[2-(4-alkoxyphenyl)ethynyl]phenylene units. The electrophile-induced cyclization reactions are directed away from the bridgehead carbon atoms of triptycene by steric factors, thereby producing one-handed twisted ladder units without any detectable byproducts. Moreover, the quantitative and regioselective nature of this intramolecular cyclization allowed us to synthesize optically active ladder polymers with a well-defined one-handed helical geometry in which homoconjugated dibenzo[a,h]anthracene units are helically arranged along the main chain. This synthesis route enables the construction of a variety of nanoscale helical ladder architectures and provides an entry into new chiroptical materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据