期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 7, 页码 3116-3120出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b12282
关键词
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资金
- Netherlands Organisation for Scientific Research through a VICI grant [724.014.003]
A recently discovered photodecarboxylase from Chlorella variabilis NC64A (CvFAP) bears the promise for the efficient and selective synthesis of hydrocarbons from carboxylic acids. CvFAP, however, exhibits a clear preference for long-chain fatty acids thereby limiting its broad applicability. In this contribution, we demonstrate that the decoy molecule approach enables conversion of a broad range of carboxylic acids by filling up the vacant substrate access channel of the photodecarboxylase. These results not only demonstrate a practical application of a unique, photo-activated enzyme but also pave the way to selective production of short-chain alkanes from waste carboxylic acids under mild reaction conditions.
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