期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 8, 页码 3385-3389出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b13397
关键词
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资金
- German Research Council (DFG) [KO-2288/26-1, INST 1841154-1FUGG]
- Jacobs University
- CMST COST Action (PoCheMoN) [CM1203]
- German Academic Exchange Council (DAAD)
- German Chemical Industry Fund (FCI)
Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)(8)H-6](8-) decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.
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