期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 5, 页码 1828-1832出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b13652
关键词
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资金
- Robert A. Welch Foundation [F-0038]
- NIH-NIGMS [RO1-GM069445]
- Eli Lilly and Company
The first intermolecular carbonyl arylations via transfer hydrogenative reductive coupling are described. Using rhodium catalysts modified by (Bu2PMe)-Bu-t, sodium formate-mediated reductive coupling of aryl iodides with aldehydes occurs in a chemoselective fashion in the presence of protic functional groups and lower halides. This work expands the emerging paradigm of transfer hydrogenative coupling as an alternative to preformed carbanions or metallic reductants in C=X addition.
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