Catalytic performance of Zr-doped CuO-CeO2 oxides for CO selective oxidation in H2-rich stream

Zr-doped CuO-CeO2 catalysts for CO selective oxidation were designed and prepared by the hydrothermal method and coprecipitation. The experimental samples were characterized by means of N-2 adsorption-desorption isotherms, powder X-ray diffraction, temperature-programmed reduction and X-ray photoelectron spectroscopy. It is observed that the catalyst prepared by hydrothermal method exhibits larger specific surface area, smaller crystalline size and higher dispersion of active components compared with those of the catalyst obtained by coprecipitation. Meanwhile, redox properties of copper oxide are improved significantly and highly dispersed copper species providing CO oxidation sites are present on the surface. Furthermore, adsorptive centers of CO and active oxygen species increase on the copper-ceria interfaces. The Zr-doped CuO-CeO2 catalyst prepared by hydrothermal method possesses superior catalytic activity and selectivity for selective oxidation of CO at low temperature compared with those of the sample prepared by coprecipitation. The temperature corresponding to 50% CO conversion is only 73 degrees C and the temperature span of total CO conversion is expanded from 120 to 160 degrees C. (C) 2019 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.