期刊
JOURNAL OF POWER SOURCES
卷 414, 期 -, 页码 453-459出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2019.01.038
关键词
Lithium-sulfur batteries; Sulfur vacancies; Active sites; High sulfur loading; In situ oxidation-refilling; Polysulfide conversion
资金
- National Natural Science Foundation of China [21477046, 21876061]
- Key Technology RAMP
- D Program of Shandong Province [2016ZDJS11A03]
Sulfides are one of the most fascinating cathodic candidates for lithium-sulfur batteries (LSBs). However, low sulfur contents, dissolution of lithium polysulfides (LiPSs) into the electrolyte and slow conversion kinetics are key challenges for commercialization of sulfided-based LSBs. Herein, massive active sites are fabricated by creating sulfur vacancies on zinc sulfide (ZnS) dispersed on reduced graphene oxide (rGO) (ZnS1-x/rGO) and subsequent in situ oxidation-refilling loading strategy, which allows for 90 wt% sulfur contents. X-ray photoelectron spectroscopy (XPS), electrocatalytical experiments and density functional theory (DFT) confirm that sulfur vacancies act as efficient adsorption and catalytic conversion sites for LiPSs. The S-ZnS1-x/rGO cathode exhibits 1168 mAh g(-1) capacity and similar to 100% Coulombic efficiency with a capacity decay rate of 0.02% per cycle only at 0.5C after 500 cycles, one of the best performance reported up to date. Remarkably, high performances are retained even at 4.5 mg cm(-2) areal sulfur loading.
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