期刊
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
卷 125, 期 -, 页码 57-63出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2018.10.012
关键词
Nanoporous carbon; N-doping; Metal-organic framework; Supercapacitor; Hierarchical structure
资金
- National Key R&D Program of China [2017YFD0601006]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Youth Fund of Natural Science Foundation of Jiangsu Province [BK20170919]
- Scientific Research Foundation for Returned Scholars from Nanjing Forestry University [GXL2018014]
ZIF-8 wrapped two-dimensional ZIF-L(Co) was prepared. By adjusting the Zn2+ concentration in precursor, ZIF8 layer with different thickness was coated onto sheet-like ZIF-L. After carbonization, hierarchical porous carbon with CNTs wrapping was formed. Proper ZIF-8 coating would result in the porous carbon with relative high BET surface area, N content, electrical conductivity and proper pore size distribution; thus showing higher super capacitive performance than that of carbonized ZIF-8 or carbonized ZIF-L. The highest specific capacitance is 274 F/g for carbonized composite materials compared to that of 220 F/g for carbonized ZIF-8 and 57 F/g for carbonized ZIF-L. Moreover, such composite sample (CZ-6) showed high stability and the energy density reached 6.99 W h/kg at a power density of 0.262 kW/k, which is better than most of other ZIF-based porous carbon reported before.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据