期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 5, 页码 2779-2785出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b03170
关键词
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资金
- NSFC [21702117, 21878167]
- National Key Research and Development Program [2017YFE0105200]
- Natural Science Foundation of Shandong Province [JQ201604, ZR2017BB005]
- Key Research and Development Program of Shandong Province [2017GSF218073]
An organocatalytic C(sp(3))-H functionalization of 5-methyl-2,3-dihydrofuran derivatives with trifluoropyruvates was achieved via a sequential exo-tautomerization/carbonyl-ene process, providing the biologically important CF3-substituted 2,3-dihydrofurans in high yields. This method featured mild metal-free conditions, good chemoselectivity, and easy scalability.
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