期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 4, 页码 2366-2371出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b03242
关键词
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资金
- National Natural Science Foundation of China [21602123]
- Foundation of Hubei Key Laboratory of Natural Products Research and Development [NPRD 2018007]
This paper reports the tandem reaction strategy of the Passerini/Staudinger/aza-Wittig reaction based on the in situ capture of isocyanides. According to this strategy, isocyanides are synthesized in situ and immediately work as the substrate for the Passerini reaction and postmodification tandem reaction in one pot. In addition, two types of new compounds, 5-oxo-3,5-dihydrobenzo[e][1,4]oxazepines and 6-oxo-5,6-dihydro-2H-1,4-oxazines, were synthesized using the tandem reaction strategy that includes five-step transformations in one pot.
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