期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 7, 页码 4458-4466出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b03192
关键词
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资金
- National Natural Science Foundation of China [21778025, 21762021]
- Science and Technology Project of Jiangxi Provincial Education Department [GJJ150297, GJJ150324]
A robust transition-metal-free one-step strategy for the synthesis of ynamides from sulfonamides and (Z)-1,2-dichloroalkenes or alkynyl chlorides is presented. This method is not only effective for internal ynamides but also amenable for terminal ynamides. Various functional groups, even the vinyl moiety, are compatible, and thus, this strategy offers the opportunity for further functionalization.
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