期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 29, 期 5, 页码 1565-1574出版社
SPRINGER
DOI: 10.1007/s10904-019-01120-4
关键词
Electrochemical synthesis; Metal-organic framework; Ni-3(BTC)(2); Ni foam; Hydrogen evolution reaction; Electrocatalyst
资金
- Research Council of the Iran University of Science and Technology
In this work, Ni-3(BTC)(2) metal-organic framework (MOF) based on the nickel (II) and benzene 1,3,5-tricarboxylic acid (H3BTC) was synthesized on a nickel foam (NiBTC/Ni foam) using an electrochemical synthesis technique. This technique allows the formation of crystal layers overgrowing the porous Ni support at the room temperatures in a short synthesis time. The influence of some important parameters such as solvent, voltage, and synthesis time on the MOF production was investigated. The structure and morphology of the MOFs were characterized by X-ray diffraction and scanning electron microscopy. The coordination between nickel (II) and carboxylate moieties of the linker has been characterized using Fourier transform infrared spectroscopy, and the surface area of the MOF was measured by Brunauer-Emmett-Teller nitrogen adsorption-desorption technique. The thermal stability was examined with thermal gravimetric analysis method. After synthesis and characterizations, the performance of Ni foam and NiBTC/Ni foam for the electrochemical hydrogen evolution reaction (HER) were compared by the linear sweep voltammetry, electrochemical impedance spectroscopy, and the chronoamperometry. The results showed that NiBTC/Ni foam has a more catalytic activity for HER.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据