期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 365, 期 -, 页码 744-750出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2018.11.031
关键词
Catalytic ozonation; Fe2+ -modified goethite; Surface hydroxyl groups; Hydroxyl radicals
资金
- National Key R&D Program of China [2017YFA0207203]
- National Natural Science Foundation of China [51208186, 51608362]
- Open Project of State Key Laboratory of Urban Water Resource and Environment [HCK201711]
- HAS Fund for Distinguished Young Scholars [CXJQ2018ZR02]
In this study, Fe2+-modified goethite with low defects (alpha-Fe(Fe2+)OOH) was synthesized and characterized. Results revealed that alpha-Fe(Fe2+)OOH is a nano magnetic material with goethite (alpha-FeOOH)-type structures and has fewer Lewis acid of Fe3 on its surface. Moreover, alpha-Fe(Fe2+)OOH was effective in catalytic ozonation of 4-chloronitrobenzene (4-CNB), which is a probe contaminant that cannot be efficiently removed through sole ozonation. The removal of 4-CNB increased with ozone concentration and alpha-Fe(Fe2+)OOH dosage, but decreased with the presence of carbonate, sulfate and phosphate. The catalytic activity of alpha-Fe(Fe2+)OOH also showed a dependence on solution pH. The presence of humic acid accelerated 4-CNB removal at low concentration but inhibited the removal at high concentration. In comparison with alpha-FeOOH, alpha-Fe(Fe2+)OOH significantly enhanced hydroxyl radicals generation and reduced Fe ions release in this process. The hydroxyl groups of Fe3+ on alpha-FeOOH and alpha-Fe(Fe2+)OOH surface was active site for ozone decomposition into hydroxyl radicals. Introducing Fe2+ significantly increased the density of surface hydroxyl groups relative to alpha-FeOOH. This enhancement significantly promoted hydroxyl radicals generation and 4-CNB degradation in the solution.
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