期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 365, 期 -, 页码 81-87出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2018.11.001
关键词
Nuclear fuel reprocessing; Iodine-129; Bi-Bi2O3-TiO2-C; Adsorption
资金
- Scientific Research Fund of Sichuan Provincial Education Department [17ZA0403]
- Mianyang Science and Technology Program [17YFCL001]
- Doctoral Research Fund of Southwest University of Science and Technology [16ZX7156]
- One-Thousand-Talents Scheme in Sichuan Province
- Hebei Outstanding Young Scholars, Science and Technology Program of Hebei Province [D2016403064, 16044601Z]
- Hebei Science and Technology Support Program [15211121]
The Bi-Bi2O3-TiO2-C composites were prepared by a sol-gel method and investigated for capturing iodine-129 (1291) in off-gas producing from spent fuel reprocessing. Firstly, the optimal process conditions were operated through the orthogonal experiments, showing that the capturing capacity of the optimal composite was calculated about 504.0 +/- 19.5 mg/g, which is approximately 2.0-fold higher than that of the commercial silver exchanged zeolites (AgX). Secondly, the structure and morphology of the Bi-Bi2O3-TiO2-C composite were characterized, suggesting that the Bi is regularly spherical in the shape, coating by the Bi2O3, TiO2 and amorphous carbon. Finally, the mechanism for the iodine adsorption in the Bi-Bi2O3-TiO2-C system was revealed, demonstrating that the iodine was captured by physisorption and chemisorption.
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