期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 540, 期 -, 页码 39-50出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2018.12.106
关键词
NiO; Meshed nanowalls; H2S gas; Gas sensor; Sensing mechanism
资金
- National Natural Science Foundation of China [21771060, 61271126, 21305033]
- International Science & Technology Cooperation Program of China [2016YFE0115100]
- Program for Science and Technology Project of Heilongjiang province [B2015008]
- Heilongjiang University
- Innovation Research Project [YJSCX2018-017HLJU]
Novel NiO meshed nanowalls, with characteristics of open geometry, porosity, single crystal and highly crystalline framework, are grown in situ on different substrates (including Al2O3 tube, glass slide, ITO, stainless steel mesh, nickel foam and carbon cloth) via a simple ammonia volatilization liquid deposition process at room temperature and a postcalcination treatment. The calcination temperature can strongly influence the pore size and crystallinity of the product, leading to different gas-sensing performances. The product that obtained at 700 degrees C (NiO-700) has the advantage in the combination of the largest pore size and high crystallinity, and shows the highest response to H2S gas. In 0.01-100 ppm H2S gas, the NiO-700 meshed nano walls based sensor can give evident and reversible response signals at a low optimal operating temperature of 50 degrees C, the response towards 100 ppm H2S can reach to 137.3, the detection limit is as low as 10 ppb. Furthermore, the sensor also exhibits excellent selectivity, repeatability, anti-humidity and long-term stability for H2S detection. The results of gas chromatograph-mass spectrometry (GC-MS) and infrared gas analysis (IRGA) reveal that the H2S gas can be oxidized to SO2 after interacting with NiO-700 meshed nanowalls material. Therefore, the possible H2S sensing mechanism should be proposed as: H2S gas molecules undergo a redox reaction with adsorbed oxygen anion on the surface of NiO-700 meshed nanowalls to form SO2; meanwhile, the electrons restricted by adsorbed oxygen return to the bulk and recombine with the holes, resulting in a decrease in effective carrier concentration of holes and thus generating a change in resistance. (C) 2019 Elsevier Inc. All rights reserved.
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