期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 538, 期 -, 页码 34-44出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2018.11.080
关键词
NiCo2S4@NiCoP nanocolumn; Charge storage kinetics; Supercapacitors; Electrochemical performance
资金
- National Natural Science Foundation of China, China [51572218, 61601342]
- Key Project of Research and Development of Shaanxi Province, China [2018ZDCXL-GY-08-05]
- Key Science and Technology Innovation Team Project of Natural Science Foundation of Shaanxi Province, China [2017KCT-01]
- International Cooperative Program, China [201410780]
- Northwest University Cross-discipline Fund for Postgraduate Students, China [YZZ17105]
A novel hierarchical core-shell nanocolumn array, with NiCo2S4 hollow nanowire (NiCo2S4 H-NW) as the core and NiCoP nanosheet (NiCoP NS) as the shell, has been directly synthesized on nickel foam (NF) as self-supported, binder-free electrode for high-performance supercapacitors. The morphological characterizations reveal that the diameter of NiCo2S4 H-NW core is similar to 100 nm and the diameter of single NiCo2S4@NiCoP core-shell nanocolumn is similar to 250 nm. Through a series of electrochemical tests and the analysis of charge storage kinetics, hierarchical NiCo2S4@NiCoP/NF electrode presents high areal specific capacitance of 5.98 F/cm(2) at 1 mA/cm(2), outstanding rate capability (70.29% capacitance retention with the current density increased from 1 to 50 mA/cm(2)) and superior cycling stability (92.94% of original capacity is retained after 5000 cycles at 10 mA/cm(2)). The prominent performance of NiCo2S4@NiCoP/NF electrode could be resulted from their unique hierarchical core-shell nanocolumn structure, which could offer abundant active sites near the interface for fast electrochemical reaction, and validly avoid the collapse of internal structure for the stability of whole structure in the repeated electrochemical measurement. The novel NiCo2S4@NiCoP/NF electrode offers a new method for future electrochemical energy storage devices with high-stability. (C) 2018 Elsevier Inc. All rights reserved.
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