Synthesis of a zinc-based metal-organic framework with histamine as an organic linker for the dispersive solid-phase extraction of organophosphorus pesticides in water and fruit juice samples

As a highly efficient adsorbent, the zinc-based metal-organic framework has been successfully synthesized from zinc as the metal ion and histamine as an organic linker under solvothermal conditions. The structure of nanocomposite was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) analysis. The synthesized sorbent was applied for dispersive solid-phase extraction (DSPE) of organophosphorus pesticides (OPPs) in fruit juice and water samples. The gas chromatography-flame ionization detector (GC-FID) was used as instrument detection. The main experimental factors affecting the extraction efficiency such as the desorption conditions, sorbent amount and extraction time were evaluated and optimized. Good linearity exhibited for all of the target analytes in the 0.1-100 ng mL(-1) concentration range. The enrichment factors (EFs) ranged from 803 to 914. The limits of detection (LODs) for the established DSPE-GC-FID method were found to be 0.03-0.21 ng mL(-1). The DSPE-GC-FID method can be used for the analysis of OPPs in water and fruit juice samples with recoveries of the analytes in the range of 91.9% to 99.5%. (C) 2019 Elsevier B.V. All rights reserved.